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Natural sugar, starch and carb blockers are dietary supplements that help inhibit the absorption of starch and carbohydrates from food that is eaten. Carb blockers are actually starch-enzyme blockers. They inhibit the body's production of alpha-amylase, the enzyme that digests starch. With less alpha-amylase produced, the body is less able to break down starches into sugar (glucose) for further digestion.